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Publicatie

Efficient ruthenium-catalysed S-S, S-Si and S-B bond forming reactions

Tijdschriftbijdrage - Tijdschriftartikel

[RuCl(PPh3)(2)(3-phenylindenyl)] (1) has been shown to be an efficient catalyst in thiol dehydrogenative coupling to give disulfides. Moreover, an efficient procedure for the preparation of silylthioethers and thioboranes is presented. Complex 1 demonstrated a great ability to catalyse the coupling of thiols with silanes and boranes under mild conditions with excellent results (turnover number up to 200).
Tijdschrift: CHEMICAL COMMUNICATIONS
ISSN: 1359-7345
Issue: 52
Volume: 49
Pagina's: 5829 - 5831
Jaar van publicatie:2013