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Iron-catalyzed aerobic oxidation of (Alkyl)(aryl)azinylmethanes
Tijdschriftbijdrage - Tijdschriftartikel
An iron-catalyzed aerobic oxidation of (alkyl)(aryl)azinylmethanes has been developed leading to tertiary alcohols in moderate to good yields. Hock rearrangement was identified as a major side reaction leading to a complex mixture of undesired products. Addition of thiourea sometimes allows inhibiting this side reaction and steers the reaction towards the desired products.
Tijdschrift: Synlett : accounts and rapid communications in synthetic organic chemistry
ISSN: 0936-5214
Volume: 28
Pagina's: 1564 - 1569
Jaar van publicatie:2017
Trefwoorden:A1 Journal article
BOF-keylabel:ja
BOF-publication weight:1
CSS-citation score:1
Authors from:Higher Education
Toegankelijkheid:Open