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Separation of rare earths by non-aqueous solvent extraction KU Leuven
Solvent extraction is widely used for the separation of mixtures of rare earths on an industrial scale. However, these separation processes are not very efficient so that many extraction stages are required to produce pure rare earths. In this project, we develop a new approach to separation of rare earths: non-aqueous solvent extraction with two immiscible organic phases. Non-aqueous solvent extraction offers some advantages compared to ...
Separation of rare-earth ions from ethylene glycol (+LiCl) solutions by non-aqueous solvent extraction with Cyanex 923 KU Leuven
The separation of a mixture of rare earths by non-aqueous solvent extraction with two immiscible organic phases has been studied. The more polar organic phase was ethylene glycol with dissolved lithium chloride and the less polar organic phase was the extractant diluted in n-dodecane. Cyanex 923 was found to be the most performant extractant amongst the investigated acidic, basic and solvating extractants: Cyanex 272, Cyphos IL 101, Aliquat 336, ...
Non-aqueous solvent extraction of rare-earth nitrates from ethylene glycol to n-dodecane by Cyanex 923 KU Leuven
A solvent extraction process comprising two immiscible organic phases has been developed for the extraction of rare earths. The more polar organic phase was ethylene glycol with dissolved rare-earth nitrate salts and lithium nitrate, while the less polar phase was a solution of the neutral extractant Cyanex® 923 dissolved in n-dodecane. The solvent extraction mechanism was determined by slope analysis and the main species in the organic phase ...
Separation of transition metals from rare earths by non-aqueous solvent extraction from ethylene glycol solutions using Aliquat 336 KU Leuven
Solvent extraction is a widely used separation technique in extractive metallurgy. A conventional solvent extraction system consists of an aqueous phase and an immiscible organic phase. In this work, we show that replacement of water by a polar organic solvent can lead to superior metal separations. Cobalt(II) and samarium(III) chlorides dissolved in water and ethylene glycol (EG), respectively, with LiCl as chloride source, were extracted by ...
Non-aqueous solvent extraction of indium from an ethylene glycol feed solution by the ionic liquid Cyphos IL 101: speciation study and continuous counter-current process in mixer-settlers KU Leuven
A solvometallurgical process for the separation of indium(iii) and zinc(ii) from ethylene glycol solutions using the ionic liquid extractants Cyphos IL 101 and Aliquat 336 in an aromatic diluent has been investigated. The speciation of indium(iii) in the two immiscible organic phases was investigated by Raman spectroscopy, infrared spectroscopy, EXAFS and 115In NMR spectroscopy. At low LiCl concentrations in ethylene glycol, the bridging ...
Nonaqueous Solvent Extraction for Enhanced Metal Separations: Concept, Systems, and Mechanisms KU Leuven
Efficient and sustainable separation of metals is gaining increasing attention, because of the essential roles of many metals in sustainable technologies for a climate-neutral society, such as rare earths in permanent magnets and cobalt, nickel, and manganese in the cathode materials of lithium-ion batteries. The separation and purification of metals by conventional solvent extraction (SX) systems, which consist of an organic phase and an ...
Enhanced Separation of Neodymium and Dysprosium by Nonaqueous Solvent Extraction from a Polyethylene Glycol 200 Phase Using the Neutral Extractant Cyanex 923 KU Leuven
Neodymium and dysprosium can be efficiently separated by solvent extraction, using the neutral extractant Cyanex 923, if the conventional aqueous feed phase is largely replaced by the green polar organic solvent polyethylene glycol 200 (PEG 200). While pure aqueous and pure PEG 200 solutions in the presence of LiCl or HCl were not able to separate the two rare earth elements, high separation factors were observed when extraction was performed ...