Double Hangman Iron Porphyrin and the Effect of Electrostatic Nonbonding Interactions on Carbon Dioxide Reduction KU Leuven
Hangman porphyrins influence the reaction rates of small molecule activation by positioning a functional group in the secondary coordination sphere of the metal center. Electrocatalysis by hangman porphyrins has examined only one face modification of the macrocycle with a hanging group, thus allowing for circumvention of secondary sphere effects by reaction of the small molecule on the opposite face of the hangman cleft. We now report the ...