Design of Cu-based MIL-100(Fe) catalyst for propylene-selective catalytic reduction of NOx : combination of activity, characterizations and mechanism Ghent University
The hydrothermal technique was applied to prepare a new metal–organic framework, MIL-100(Fe), which was modified by ultrasonic impregnation with different wt % of copper. The results showed that the NOx conversion over 2.3Cu-MIL-100(Fe) was 100 % at 275 °C and maintained at ≥ 85 %, with N2 selectivity ≥ 90 % in the temperature range of 275–400 °C and high SO2 resistance. An increase in the Cu content up to 2.3 wt% showed the highest surface area ...