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A study of the electron transfer inhibition on a charged self-assembled monolayer modified gold electrode by odd random phase multisine electrochemical impedance spectroscopy Vrije Universiteit Brussel
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A Unified Perspective on the Hydrogen Atom Transfer and Proton-Coupled Electron transfer Mechanisms in Terms of Topographic Features of the Ground and Excited Potential Energy Surfaces as Exemplified by the Reaction Between Phenols and Radicals KU Leuven
The relation between the hydrogen atom transfer (HAT) and proton-coupled electron transfer (PCET) mechanisms is discussed and is illustrated by multiconfigurational electronic structure calculations on the ArOH + R(*) --> ArO(*) + RH reactions. The key topographic features of the Born-Oppenheimer potential energy surfaces that determine the predominant reaction mechanism are the conical intersection seam of the two lowest states and reaction ...
Electrochemical treatment of graphite to enhance electron transfer from bacteria to electrodes Ghent University
Estimation of Rates of Reactions Triggered by Electron Transfer in Top-Down Mass Spectrometry Hasselt University University of Antwerp
Electron transfer dissociation (ETD) is a versatile technique used in mass spectrometry for the high-throughput characterization of proteins. It consists of several concurrent reactions triggered by the transfer of an electron from its anion source to sample cations. Transferring an electron causes peptide backbone cleavage while leaving labile post-translational modifications intact. The obtained fragmentation spectra provide valuable ...
Estimation of Rates of Reactions Triggered by Electron Transfer in Top-Down Mass Spectrometry Hasselt University University of Antwerp
Electron transfer dissociation (ETD) is a versatile technique used in mass spectrometry for the high-throughput characterization of proteins. It consists of several competing reactions triggered by the transfer of an electron from its anion source to the sample cations. One can retrieve relative quantities of the products from mass spectra. We present a method to analyze these results from the perspective of the reaction kinetics. A formal ...
Electron Transfer Interactome of Cytochrome c Vrije Universiteit Brussel
Lying at the heart of many vital cellular processes such as photosynthesis and respiration, biological electron transfer (ET) is mediated by transient interactions among proteins that recognize multiple binding partners. Accurate description of the ET complexes - necessary for a comprehensive understanding of the cellular signaling and metabolism - is compounded by their short lifetimes and pronounced binding promiscuity. Here, we used a ...
Effects of hole and electron trapping on organic field-effect transistor transfer characteristic Hasselt University
Routine organic field-effect transistor measurements are performed at negative and positive gate voltages leading to the occurrence of both hole and electron trapping. Despite this fact, the big majority of studies have focused either on hole trapping or on electron trapping but not on both at the same time. This paper presents the influences of trapped electron concentration n(trap) and trapped hole concentration p(trap) on the transfer ...