Chirality from scratch: enantioselective adsorption in geometrically controlled lateral nanoconfinement

Chiral symmetry breaking in molecular adsorption at the solid/liquid interface by lateral geometric nanoconfinement is demonstrated. The chiral nanoconfinement is created at the interface of achiral covalently modified highly-oriented pyrolytic graphite and a racemate by in situ scanning probe lithography. Enantioselective adsorption of chiral molecules is achieved by adjusting the relative orientation between the nanoconfining walls and substrate symmetry direction.

Publication year:2021

BOF-keylabel:yes

IOF-keylabel:yes

BOF-publication weight:2

CSS-citation score:1

Authors:International

Authors from:Higher Education

Accessibility:Open