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Photoredox-Catalyzed Hydrosulfonylation of Arylallenes

Journal Contribution - Journal Article

(Het)Arylallenes undergo hydrosulfonylation under photoredox-catalyzed conditions. The reaction gives vinyl sulfones in a regio- and diastereoselective manner, employing sodium sulfinates as the sulfonyl source and eosin Y as the photocatalyst. Indol-1-yl, pyrrol-1-yl, phenyl, and naphtylallenes might be used. Aliphatic allenes are incompatible with the reaction conditions.
Journal: Journal of Organic Chemistry
ISSN: 0022-3263
Issue: 4
Volume: 85
Pages: 2250 - 2259
Publication year:2020
BOF-keylabel:yes
IOF-keylabel:yes
BOF-publication weight:2
CSS-citation score:3
Authors:International
Authors from:Higher Education
Accessibility:Open