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Homocoupling defects in porphyrinoid small molecules and their effect on organic solar cell performance

Journal Contribution - Journal Article

Porphyrinoid small molecules can be used as electron donor or acceptor components in bulk heterojunction organic solar cells, which has resulted in steadily improving power conversion efficiencies. However, the effect of material purity is often neglected. In this work, a series of D1-A-π-D2-π-A-D1 conjugated chromophores based on the A2B2-meso-ethynylporphyrin core is synthesized. Different electron-donating (D1) end groups are chosen to investigate their influence on the material properties and optoelectronic characteristics. The porphyrin small molecules are tested as electron donor materials in bulk heterojunction organic solar cells in combination with PC71BM, affording an efficiency up to 4.6% under standard illumination. Furthermore, it is shown that (Glaser type) homocoupled side products are generated during the final Sonogashira cross-coupling reactions, which can be very challenging to remove. Their presence reduces solar cell performance by affecting the open-circuit voltage and fill factor.
Journal: Organic Electronics
ISSN: 1566-1199
Volume: 69
Pages: 48 - 55
Publication year:2019
Keywords:Porphyrins, Conjugated small molecules, Organic photovoltaics, Material purity, Homocoupling, Glaser
BOF-keylabel:yes
IOF-keylabel:yes
BOF-publication weight:2
CSS-citation score:1
Authors from:Government, Higher Education, Private
Accessibility:Open