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Project

Atomic scale synthesis and atomic scale characterization of complex oxides with electronic/ionic conductivity

Complex oxides that exhibit electronic/ionic conductivity are essential for a wide range of applications, e.g. as transparent conductors in photovoltaics and flexible electronics, or as an ion conducting solid electrolyte for Li ion batteries. The electronic/ionic conductivity is determined by structural properties at the atomic scale. Therefore, atomic scale control during synthesis and atomic scale characterization of the elemental distribution and migration of elemental species is essential. Within this project, we aim to investigate synthesis strategies based on atomic layer deposition (ALD) for achieving complex oxides with tunable electronic and ionic conductivity. ALD can be considered as additive manufacturing at the atomic scale, where (sub)monolayers can be deposited onto complex shaped surfaces in a highly controlled way. Secondly, we aim to perform atomic scale characterization through atom probe tomography (APT). In APT a tip-shaped sample is peeled off, atom by atom, and each atom is ‘weighed’ allowing us to identify which element it is, providing a full 3D atomic scale reconstruction of the sample. The combined use of ALD and APT will enable us to obtain a fundamental understanding of the correlation between the atomic-scale 3D-compositional distribution and the electronic/ionic conductivity. Conversely, the atomic scale control offered by ALD will enable us to obtain unique model systems to unravel the underlying physics of APT on poorly conducting materials.

Date:1 Jan 2018 →  31 Dec 2021
Keywords:Complex oxides, Electronic conductivity, Ionic conductivity, Atomic layer disposition, Atomic scale, Atom probe tomography
Disciplines:Classical physics, Elementary particle and high energy physics, Other physical sciences